• Rob Stecker

The Dirty Dozen - Part 10: Siloxanes

Updated: Apr 10, 2018


Use in Cosmetics


These silicone-based compounds are used in cosmetics to soften, smooth, and moisten. They make hair products dry more quickly and deodorant creams slide on more easily. They are also used extensively in moisturizers and facial treatments. Siloxanes can also be found in medical implants, water-repelling windshield coatings, building sealants and lubricants.


Health and Environmental Hazards


Environment Canada assessments concluded that cyclotetrasiloxane and cylcopentasiloxane — also known as D4 and D5 — are toxic, persistent, and have the potential to bioaccumulate in aquatic organisms i, ii

Also, the European Union classifies D4 as a endocrine disruptor, based on evidence that it interferes with human hormone function, iii

and a possible reproductive toxicant that may impair human fertility. iv


In laboratory experiments, exposure to high doses of D5 has been shown to cause uterine tumours and harm to the reproductive and immune systems. D5 can also influence neurotransmitters in the nervous system. v


Structurally similar to D4 and D5, cyclohexasiloxane (or D6) is also persistent and has the potential to bioaccumulate. Environment Canada’s assessment of D6 concluded that this third siloxane is not entering the environment in a quantity or concentration that endangers human health or the environment but noted significant data gaps concerning its toxicity. vi.


Cyclomethicone is a mixture of D4, D5, and D6 siloxanes.


Regulatory Status


January 2009, Environment Canada and Health Canada proposed to add D4 and D5 siloxanes to the List of Toxic Substances pursuant to the Canadian Environmental Protection Act, 1999 (CEPA), and to develop regulations “to limit the quantity or concentration of D4 and D5 in certain personal care products.” vii In addition, under CEPA, anyone proposing a “significant new activity” involving siloxanes must notify the Minister of the Environment. However, there are currently no restrictions on these ingredients in cosmetics.


Related Ingredients


Polydimethylsiloxane (PDMS) silicone polymers are produced from D4 and contain residual amounts of D4 and D5. Dimethicone is a common PDMS ingredient in cosmetics.

i Environment Canada and Health Canada. _Screening Assessment for the Challenge Octamethylcyclotetrasiloxane (D4)_. November 2008. http://www.ec.gc.ca/substances/ese/eng/challenge/batch2/batch2_556-67-2.cfm ii Environment Canada and Health Canada. Screening Assessment for the Challenge: Decamethylcyclopentasiloxane (D5). November 2008. http://www.ec.gc.ca/substances/ese/eng/challenge/batch2/batch2_541-02-6.cfm iii DHI Water and Environment. Study on Enhancing the Endocrine Disrupter Priority List with a Focus on Low Production Volume Chemicals. Revised Report to DG Environment. Hersholm, Denmark: DHI, 2007. http://ec.europa.eu/environment/endocrine/documents/final_report_2007.pdf iv European Commission. Regulation (EC) 1272/2008 , Annex VI, Table 3.2. Sep 2009. http://ecb.jrc.ec.europa.eu/classification-labelling/ v California. Office of Environmental Health Hazard Assessment. Cyloxanes. Materials for the December 4-5, 2008, Meeting of the California Environmental Contaminant Biomonitoring Program Scientific Guidance Panel. http://oehha.ca.gov/multimedia/biomon/pdf/1208cyclosiloxanes.pdf vi Environment Canada and Health Canada. Screening Assessment for the Challenge: Dodecamethylcyclohexasiloxane (D6). November 2008. http://www.ec.gc.ca/substances/ese/eng/challenge/batch2/batch2_540-97-6.cfm vii Environment Canada and Health Canada. Proposed Risk Management Approach for Cyclotetrasiloxane, cotamethyl- (D4) and Cyclopentasiloxane, decamethyl- (D5). Jan 2009. http://www.ec.gc.ca/substances/ese/eng/challenge/batch2/batch2_541-02-6_rm.cfm




Original Wellness is a team of people that continues to grow and provide support and alternatives for people making these choices every day. It is too much to carry alone, if you have questions and looking for people who have reasonable solutions contact us at https://www.originalwellness.net/ or https://www.facebook.com/groups/Livingascreated/ or you can even email me directly at robstecker26@gmail.com

THANKS to the David Suzuki Foundation “One Nature” for this great work

https://davidsuzuki.org/queen-of-green/dirty-dozen-cosmetic-chemicals-avoid/

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